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Publicly Available Published by De Gruyter October 29, 2009

Chemical speciation of environmentally significant metals with inorganic ligands. Part 3: The Pb2+ + OH–, Cl–, CO32–, SO42–, and PO43– systems (IUPAC Technical Report)

  • Kipton J. Powell , Paul L. Brown , Robert H. Byrne , Tamás Gajda , Glenn Hefter , Ann-Kathrin Leuz , Staffan Sjöberg and Hans Wanner

Abstract

Complex formation between PbII and the common environmental inorganic ligands, Cl, OH, CO32–, SO42–, and PO43–, can be significant in natural waters with low concentrations of organic matter. Numerical modeling of the speciation of PbII amongst these inorganic ligands requires reliable values for the relevant stability (formation) constants. This paper provides a critical review of such constants and related thermodynamic data. It recommends values of log10 βp,q,r° valid at Im = 0 mol kg–1 and 25 °C (298.15 K), along with the equations and empirical coefficients required to calculate log10βp,q,r values at higher ionic strengths using the Brønsted–Guggenheim–Scatchard specific ion interaction theory (SIT). Some values for reaction enthalpies, ΔrH, are also reported. In weakly acidic fresh water systems (–log10 {[H+]/} < 6), the speciation of PbII is similar to that of CuII. In the absence of organic ligands, PbII speciation is dominated by Pb2+(aq), with PbSO4(aq) as a minor species. In weakly alkaline solutions, 8.0 < –log10 {[H+]/} < 9.0, the speciation is dominated by the carbonato species PbCO3(aq) and Pb(CO3)22–. In weakly acidic saline systems (–log10 {[H+]/} < 6), the speciation is dominated by PbCln(2–n)+ complexes, (n = 0–3), with Pb2+(aq) as a minor species. In this medium (and in seawater), the speciation contrasts with that of CuII because of the higher stability of the Pb2+-chlorido- complexes. In seawater at –log10 {[H+]/} = 8.2, the calculated speciation is less well defined, although it is clearly dominated by the uncharged species PbCO3(aq) (41 % of [Pb]T) with a significant contribution (16 %) from Pb(CO3)Cl and minor contributions (5–10 %) from PbCln(2–n)+, (n = 0–3) and Pb(CO3)22–. The uncertainty in calculations of PbII speciation in seawater arises from (a) the large uncertainty in the stability constant for the apparently dominant species PbCO3(aq), (b) the reliance on statistical predictions for stability constants of the ternary species Pb(CO3)Cl and Pb(CO3)OH, and (c) the uncertainty in the stability constant for PbCl42–, the available value being considered "indicative" only. There is scope for additional detailed high-quality measurements in the Pb2+ + CO32– + Cl system.


Project Year: 1999, Project Code: 1999-050-1-500


References

03BOb W. Böttger. Z. Phys. Chem.46, 521 (1903).10.1515/zpch-1903-4629Search in Google Scholar

07PLa M. Pleissner. Arb. Kaiser Gesundh.26, 384 (1907).Search in Google Scholar

08KOa F. Kohlrausch. Z. Phys. Chem.64, 129 (1908).10.1515/zpch-1908-6407Search in Google Scholar

10WOa J. K. Wood. J. Chem. Soc. 878 (1910).10.1039/CT9109700878Search in Google Scholar

13APa F. Auerbach, H. Pick. Arb. Kaiser Gesundh.45, 113 (1913).Search in Google Scholar

13KUa C. Kullgren. Z. Phys. Chem.85, 466 (1913).10.1515/zpch-1913-8518Search in Google Scholar

21GLa S. Glasstone. J. Chem. Soc. 1689 (1921).10.1039/CT9211901689Search in Google Scholar

22ARa M. P. Applebey, R. D. Reid. J. Chem. Soc. 2129 (1922).10.1039/CT9222102129Search in Google Scholar

23HEa 10.1039/tf9241900692, J. Heyrovský. Trans. Faraday. Soc.19, 692 (1923).Search in Google Scholar

28RSa 10.1021/ja01393a008, M. Randall, H. M, Spencer. J. Am. Chem. Soc.50, 1572 (1928).Search in Google Scholar

29MJa 10.1021/ja01379a004, H. Millet, M. Jowett. J. Am. Chem. Soc.51, 997 (1929).Search in Google Scholar

29TOa 10.1002/prac.19291210124, H. Töpelmann. J. Prakt. Chem.121, 320 (1929).Search in Google Scholar

31CMa 10.1021/ja01363a010, I. Cowperthwaite, V. la Mer. J. Am. Chem. Soc.53, 4333 (1931).Search in Google Scholar

32JPa 10.1039/tf9322800668, M. Jowett, H. Price. Trans. Faraday Soc.28, 668 (1932).Search in Google Scholar

34LEa A. Lebettre. J. Chim. Phys.31, 348 (1934).10.1051/jcp/1934310348Search in Google Scholar

35KAa K. Kelley, C. Anderson. Bur. Mines Bull. 384 (1935).Search in Google Scholar

37CBa J. A. Cranston, H. F. Brown. J. Royal Tech. Coll., Glasgow4, 54 (1937).Search in Google Scholar

39GVa 10.1021/ja01871a041, A. B. Garrett, S. Vellenga, C. M. Fontana. J. Am. Chem. Soc.61, 367 (1939).Search in Google Scholar

42KPa 10.1021/j150419a004, I. M. Kolthoff, R. Perlich, D. Weiblen. J. Phys. Chem.46, 561 (1942).Search in Google Scholar

45PEa K. J. Pedersen. Kgl. Danske Vid. Sels. Medd. 22, 10; 12 (1945).Search in Google Scholar

46TMa I. Tananaev, I. Mizetskaya. Zh. Anal. Khim.1, 6 (1946).Search in Google Scholar

51DCa P. Deschamps, B. Charreton. Compt. Rend.232, 162 (1951).Search in Google Scholar

52KFa I. M. Korenman, F. S. Frum, V. G. Chebakova. Zh. Obshch. Khim.22, 1771 (1952).Search in Google Scholar

55KIa P. Kivalo. Suomen Kem. B28, 155 (1955).Search in Google Scholar

54GOa G. A. Goward. A Polarographic Study of the Hydrolysis of Metal Ions, Ph.D. dissertation, Princeton University (1954).Search in Google Scholar

55AGa A. Ågren. Acta Chem. Scand. 9, 39; 49 (1955).10.3891/acta.chem.scand.09-0049Search in Google Scholar

55SIa D. Singh. J. Sci. Res. Benares Hindu Univ.6, 131 (1955).Search in Google Scholar

55VLa A. A. Vlček. Collect. Czech. Chem. Commun.20, 400 (1955).10.1135/cccc19550400Search in Google Scholar

56CHa B. Charreton. Bull. Soc. Chim. Fr.337, 347 (1956).Search in Google Scholar

57ILa 10.3891/acta.chem.scand.11-1034, N. Ingri, G. Lagerström, M. Frydman, L. G. Sillen. Acta Chem. Scand.11, 1034 (1957).Search in Google Scholar

57KLa P. Kivalo, R. Luoto. Suomen Kem. B30, 163 (1957).Search in Google Scholar

58FNa 10.3891/acta.chem.scand.12-0878, M. Frydman, G. Nilsson, T. Rengemo, L. Sillén. Acta Chem. Scand.12, 878 (1958).Search in Google Scholar

58JAa L. Jager. Chem. Listy52, 734 (1958).Search in Google Scholar

59FBa J. Faucherre, Y. Bonnaire. Compt. Rend.248, 3705 (1959).Search in Google Scholar

59OHa 10.1016/0003-2670(59)80117-3, J. W. Olver, D. N. Hume. Anal. Chim. Acta20, 559 (1959).Search in Google Scholar

59ROB R. A. Robinson, R. H. Stokes. Electrolyte Solutions, 2nd ed., p. 483, Butterworths, London (1959).Search in Google Scholar

59UGa R. Uggla. Ann. Acad. Sci. Fennicae 97 (1959).Search in Google Scholar

60COa 10.3891/acta.chem.scand.14-1999, B. Carell, Å. Olin. Acta Chem. Scand.14, 1999 (1960).Search in Google Scholar

60NMa R. Näsänen, P. Merilainen. Suomen Kem. B33, 149 (1960).Search in Google Scholar

60OLb 10.3891/acta.chem.scand.14-0126, Å. Olin. Acta Chem. Scand.14, 126 (1960).Search in Google Scholar

60OLc 10.3891/acta.chem.scand.14-0814, Å. Olin. Acta Chem. Scand.14, 814 (1960).Search in Google Scholar

60RKa 10.1021/j100837a020, B. van’t Riet, I. M. Kolthoff. J. Phys. Chem.64, 1045 (1960).Search in Google Scholar

61KOa I. Korenman. Isvest. VUZ. Khim.4, 554 (1961).Search in Google Scholar

61NMc 10.3891/acta.chem.scand.15-0913, R. Näsänen, P. Merilainen, K. Leppanen. Acta Chem. Scand.15, 913 (1961).Search in Google Scholar

61RSa 10.1021/j100820a012, R. Ramette, R. Stewart. J. Phys. Chem.65, 243 (1961).Search in Google Scholar

61NRa 10.1021/ja01463a015, C. J. Nyman, D. K. Roe, R. A. Plane. J. Am. Chem. Soc.83, 323 (1961).Search in Google Scholar

62COa 10.3891/acta.chem.scand.16-2350, B. Carell, Å. Olin. Acta Chem. Scand.16, 2350 (1962).Search in Google Scholar

62ETc A. Egorov, Z. Titova. Zh. Neorg. Khim.7, 275 (1962).Search in Google Scholar

62NMf 10.3891/acta.chem.scand.16-1549, R. Näsänen, P. Merilainen, R. Havanka. Acta Chem. Scand.16, 1549 (1962).Search in Google Scholar

62NMg R. Näsänen, P. Merilainen, L. Oja. Suomen Kem. B35, 105 (1962).Search in Google Scholar

62POa 10.3891/acta.chem.scand.16-0983, L. Pajdowski, Å. Olin. Acta Chem. Scand.16, 983 (1962).Search in Google Scholar

63MKc V. Mironov, F. Kulba, V. Fedorov, O. Tikhomirov. Zh. Neorg. Khim.8, 2536 (1963).Search in Google Scholar

63NMd R. Näsänen, P. Merilainen, M. Hyle. Suomen Kem. B36, 73 (1963).Search in Google Scholar

64FBa R. Fischer, J. Byé. Bull. Soc. Chim. Fr. 2920 (1964).Search in Google Scholar

64HUa R. Hugel. Bull. Soc. Chim. Fr. 1462 (1964).Search in Google Scholar

65HUaa R. Hugel. Bull. Soc. Chim. Fr. 968 (1965).Search in Google Scholar

65HUab R. Hugel. Bull. Soc. Chim. Fr. 971 (1965).Search in Google Scholar

65HUac R. Hugel. Bull. Soc. Chim. Fr. 2017 (1965).Search in Google Scholar

65LIc K. Lieser. Z. Anorg. Chem.339, 208 (1965).10.1002/zaac.19653390310Search in Google Scholar

66NHb 10.3891/acta.chem.scand.20-0486, L. Nilsson, G. Haight. Acta Chem. Scand.20, 486 (1966).Search in Google Scholar

66VSa F. Vierling, G. Schorsch, J. Bye. Rev. Chim. Miner.3, 875 (1966).Search in Google Scholar

67SIa 10.3891/acta.chem.scand.21-2727, G. Schorsch, N. Ingri. Acta Chem. Scand.21, 2727 (1967).Search in Google Scholar

68BAb N. Baranova. Geochem. Intl.5, 13 (1968).Search in Google Scholar

68JOH 10.3891/acta.chem.scand.22-3197, G. Johansson, Å. Olin. Acta Chem. Scand.22, 3197 (1968).Search in Google Scholar

69AWA 10.1016/S0022-0728(69)80009-4, S. A. Awad, Z. A. Elhady. J. Electroanal. Chem.20, 79 (1969).Search in Google Scholar

69BAc N. Baranova. Zh. Neorg. Khim.14, 3257 (1969).Search in Google Scholar

69DIa D. Dyrssen, E. Ivanova, K. Aren. Vest. Moskov. Univ.24, 41 (1969).Search in Google Scholar

69FFa F. Fromage, S. Fiorina. Compt. Rend.268C, 1511; 1764 (1969).Search in Google Scholar

70BIL 10.1149/1.2407606, H. W. Billhardt. J. Electrochem. Soc.117, 690 (1970).Search in Google Scholar

70GNa 10.1021/ac60289a003, G. Gardner, G. Nancollas. Anal. Chem.42, 794 (1970).Search in Google Scholar

71BHb 10.1016/S0022-0728(71)80174-2, A. Bond, G. Hefter. J. Electroanal. Chem.31, 477 (1971).Search in Google Scholar

71VIa F. Vierling. Bull. Soc. Chim. Fr. 22 (1971).Search in Google Scholar

71VIb F. Vierling. Bull. Soc. Chim. Fr. 25 (1971).Search in Google Scholar

72BHb A. Bond, G. Hefter. J. Electroanal. Chem.34, 227 (1972).Search in Google Scholar

72CBd G. Carpeni, E. Boitard, R. Pilard, S. Poize, N. J. Sabiani. J. Chim. Phys.69, 1437 (1972).Search in Google Scholar

72DHa 10.1016/0304-4203(73)90012-1, D. Dyrssen, I. Hansson. Mar. Chem.1, 137 (1972).Search in Google Scholar

72NRc 10.1021/ic50116a041, J. O. Nriagu. Inorg. Chem.11, 2499 (1972).Search in Google Scholar

72OLI 10.3891/acta.chem.scand.26-3505, Å. Olin, R. Söderquist. Acta Chem. Scand. A26, 3505 (1972).Search in Google Scholar

73BAI J. C. Bailar, H. J. Emeléus, R. Nyholm, A. F. Trotman-Dickenson. Comprehensive Inorganic Chemistry, Pergamon, Oxford (1973).Search in Google Scholar

73BHb 10.1016/S0022-0728(73)80071-3, A. Bond, G. Hefter. J. Electroanal. Chem.42, 1 (1973).Search in Google Scholar

73HHb 10.1039/dt9730001247, M. Hutchinson, W. Higginson. J. Chem. Soc., Dalton Trans. 1247 (1973).Search in Google Scholar

73NRa 10.1016/0016-7037(73)90206-8, J. O. Nriagu. Geochim. Cosmochim. Acta37, 367 (1973).Search in Google Scholar

73NRb 10.1016/0016-7037(73)90159-2, J. O. Nriagu. Geochim. Cosmochim. Acta37, 1735 (1973).Search in Google Scholar

73PPb 10.1016/0022-1902(73)80137-X, B. Pokrić, Z. Puča. J. Inorg. Nucl. Chem.35, 1987 (1973).Search in Google Scholar

73VIa F. Vierling. Ann. Chim. (France)8, 53 (1973).Search in Google Scholar

74DZc V. V. Danilov, V. S. Zaitsev, A. A. Ravdel. Zh. Prikl. Khim.47, 1930 (1974).Search in Google Scholar

74MId 10.1016/0022-1902(74)80667-6, M. Mihailov. J. Inorg. Nucl. Chem.36, 107 (1974).Search in Google Scholar

74PHc 10.4319/lo.1974.19.2.0223, R. Pytkowicz, J. Hawley. Limnol. Oceanogr.19, 223 (1974).Search in Google Scholar

74RMa 10.1016/0022-1902(74)80136-3, S. Ramamoorthy, P. G. Manning. J. Inorg. Nucl. Chem.36, 695 (1974).Search in Google Scholar

74RMb 10.1016/0022-1902(74)80644-5, S. Ramamoorthy, P. G. Manning. J. Inorg. Nucl. Chem.36, 1671 (1974).Search in Google Scholar

75EAa 10.1016/0043-1354(75)90125-6, P. Ernst, H. Allen, K. Mancy. Water Res.9, 969 (1975).Search in Google Scholar

75TUG I. A. Tugarinov, I. G. Ganeyev, I. L. Khodakovskiy. Geochem. Intl.9, 47 (1975).Search in Google Scholar

76BHa 10.1016/S0003-2670(01)82850-6, H. Bilinski, R. Huston, W. Stumm. Anal. Chim. Acta84, 157 (1976).Search in Google Scholar

76FSa V. Fedorov, L. Shishin. Zh. Fiz. Khim.50, 356 (1976).Search in Google Scholar

76SCA G. Scatchard. Equilibrium in Solution: Surface and Colloid Chemistry, Harvard University Press, Cambridge, MA (1976).Search in Google Scholar

77BLc 10.1016/S0003-2670(01)82293-5, C. Birraux, J.-C. Landry, W. Haerdi. Anal. Chim. Acta90, 51 (1977).Search in Google Scholar

78LIN 10.1021/es60148a010, C. J. Lind. Environ. Sci. Technol.12, 1406 (1978).Search in Google Scholar

78PBa S. Poddar, S. Bhattacharya, A. K. Das. Indian J. Chem., Sect. A16, 367 (1978).Search in Google Scholar

79BKa 10.1021/ac50049a018, S. Brown, B. Kowalski. Anal. Chem.51, 2133 (1979).Search in Google Scholar

80KIa 10.1246/bcsj.53.2221, T. Kawai, S. Ishiguro, H. Ohtaki. Bull. Chem. Soc. Jpn.53, 2221 (1980).Search in Google Scholar

80SBa 10.1039/dt9800001577, R. N. Sylva, P. L. Brown. J. Chem. Soc., Dalton Trans. 1577 (1980).Search in Google Scholar

80SRa 10.1016/0304-4203(80)90005-5, L. Sipos, B. Raspor, H. Nurnberg, R. Pytkowicz. Mar. Chem.9, 37 (1980).Search in Google Scholar

80SVb L.Sipos, P. Valenta, H. W. Nurnberg, M. Branica. Lead in the Marine Environment. Proceedings of International Experts Discussion, 1977, p. 61, Pergamon Press, Oxford (1980).10.1016/B978-0-08-022960-7.50011-7Search in Google Scholar

81IOa 10.1246/bcsj.54.335, S. Ishiguro, H. Ohtaki. Bull. Chem. Soc. Jpn.54, 335 (1981).Search in Google Scholar

81KOa 10.1016/0022-1902(81)80337-5, K. Kogure, M. Okamoto, H. Kakihana, M. Maeda. J. Inorg. Nucl. Chem.43, 1561 (1981).Search in Google Scholar

82BMc H. Bendiab, J. Meullemeestre, M. J. Schwing, F. Vierling. J. Chem. Res. (M) 2718 (1982).Search in Google Scholar

82BSa 10.1016/0016-7037(82)90048-5, H. Bilinski, P. Schindler. Geochim. Cosmochim. Acta46, 921 (1982).Search in Google Scholar

82ROa 10.1016/S0003-2670(01)85269-7, R. Rohl. Anal. Chim. Acta135, 99 (1982).Search in Google Scholar

82WAG D. D. Wagman, W. H. Evans, V. B. Parker, R. H. Schumm, I. Halow, S. M. Bailey, K. L. Churney, R. L. Nuttall. J. Phys. Chem. Ref. Data11, (Suppl. 2) (1982).Search in Google Scholar

83BPa M. Barrera, J. Placeres, J. Sanchez. Ann. Quim.79, 145 (1983).Search in Google Scholar

84BMb R. Byrne, W. Miller. Am. J. Sci.284, 79 (1984).Search in Google Scholar

84FCa C. Fouillac, A. Criaud. Geochem. J.18, 297 (1984).Search in Google Scholar

84MBc 10.1016/0016-7037(84)90206-0, F. Millero, R. Byrne. Geochim. Cosmochim. Acta48, 1145 (1984).Search in Google Scholar

84SEa 10.1016/0016-7037(84)90354-5, T. M. Seward. Geochim. Cosmochim. Acta48, 121 (1984).Search in Google Scholar

85BMb 10.1016/0016-7037(85)90153-X, R. Byrne, W. Miller. Geochim. Cosmochim. Acta49, 1837 (1985).Search in Google Scholar

85MMa 10.1021/ic00213a042, F. Mulla, F. Marsicano, B. S. Nakani, R. D. Hancock. Inorg. Chem.24, 3076 (1985).Search in Google Scholar

85SBa S. Shi, Y. Bai, J. Wang. Anal. Chem. (China) 646 (1985).Search in Google Scholar

86BAE C. F. Baes, R. E. Mesmer. The Hydrolysis of Cations, R. E. Krieger, Malabar, FL (1986).Search in Google Scholar

87AZa H. A. Azab. Bull. Soc. Chim. Fr. 265 (1987).Search in Google Scholar

87FGb 10.3891/acta.chem.scand.41a-0349, D. Ferri, I. Grenthe, S. Hietanen, F. Salvatore. Acta Chem. Scand. A41, 349 (1987).Search in Google Scholar

87KSd A. Khokhlova, L. Shishin, G. Chernikova, L. Rubchevskaya. Koord. Khim.13, 63 (1987).Search in Google Scholar

88FSba D. Ferri, F. Salvatore. Ann. Chim. (Rome)78, 441 (1988).Search in Google Scholar

88FSbb D. Ferri, F. Salvatore. Ann. Chim. (Rome)78, 497 (1988).Search in Google Scholar

88FSbc D. Ferri, F. Salvatore. Ann. Chim. (Rome)78, 509 (1988).10.1016/0021-9991(88)90063-0Search in Google Scholar

88PBb 10.1016/0022-0728(88)85171-4, I. Pizeta, M. Branica. J. Electroanal. Chem.250, 293 (1988).Search in Google Scholar

89FSb D. Ferri, F. Salvatore, E. Vasca. Ann. Chim. (Rome)79, 1 (1989).Search in Google Scholar

89HSa 10.1016/0022-0728(89)80121-4, A. Hannisdal, K. Schroder. J. Electroanal. Chem.263, 23 (1989).Search in Google Scholar

89NWa 10.1016/S0003-2670(00)84108-2, L. Nyholm, G. Wikmark. Anal. Chim. Acta223, 429 (1989).Search in Google Scholar

90CSa G. Chernikova, L. Shishin, A. Khokhlova. Zh. Neorg. Khim.35, 973 (1990).Search in Google Scholar

90HEa 10.1016/S0277-5387(00)86823-0, G. Hefter. Polyhedron9, 2429 (1990).Search in Google Scholar

92EDW 10.1180/minmag.1992.056.382.07, R. Edwards, R. D. Gillard, P. A. Williams, A. M. Pollard. Miner. Mag.56, 53 (1992).Search in Google Scholar

92NEa 10.3891/acta.chem.scand.46-0231, E. Neher-Neumann. Acta Chem. Scand.46, 231 (1992).Search in Google Scholar

92PKa 10.1016/0016-7037(92)90054-M, C. Paige, W. Kornicker, O. Hileman. Geochim. Cosmochim. Acta56, 1165 (1992).Search in Google Scholar

93CWa 10.1016/0039-9140(93)80171-M, J. J. Cruywagen, R. F. van de Water. Talanta40, 1091 (1993).Search in Google Scholar

93MOR F. M. M. Morel, J. G. Hering. Principles and Applications of Aquatic Chemistry, John Wiley, New York (1993).Search in Google Scholar

95CMa 10.1016/0277-5387(94)00428-H, I. Cukrowski, F. Marsicano, R. D. Hancock, P. T. Tshetlho, W. A. L. Otterlo. Polyhedron14, 1661 (1995).Search in Google Scholar

96FOa 10.1039/dt9960004597, M. Fiore, S. Orecchio, V. Romano, G. Ruggirello, R. Zingales. J. Chem. Soc., Dalton Trans. 4597 (1996).Search in Google Scholar

97GRE I. Grenthe, A. V. Plyasunov, K. Spahiu. In Modelling in Aqueous Chemistry, I. Grenthe, I. Puigdomenech (Eds.), pp. 325–426, Organisation for Economic Co-operation and Development, Paris (1997).Search in Google Scholar

99DSa C. P. Da Costa, H. Sigel. J. Biol. Inorg. Chem.4, 508 (1999).Search in Google Scholar

2000KAa 10.1016/S0020-1693(99)00435-1, Y. Kanekiyo, S. Aizawa, N. Koshino, S. Funahashi. Inorg. Chim. Acta298, 154 (2000).Search in Google Scholar

2001BRO S. A. Brown. The Aqueous Chemistry of Polonium and its Relationship to Mineral Processing Streams, Ph.D. dissertation, University of Western Sydney (2001).Search in Google Scholar

2001LEM R. J. Lemire, J. Fuger, H. Nitsche, P. Potter, M. H. Rand, J. Rydberg, K. Spahiu, J. C. Sullivan, W. J. Ullman, P. Vitorge, H. Wanner. Chemical Thermodynamics of Plutonium and Neptunium, North Holland, Amsterdam (2001).Search in Google Scholar

2001PHa 10.1021/ic001415o, W. N. Perera, G. Hefter, P. M. Sipos. Inorg. Chem.40, 3974 (2001).Search in Google Scholar PubMed

2004LIE K. H. Lieser, G. Beyer, E. Lakatos. Z. Anorg. Chem.339, 208 (2004).Search in Google Scholar

2005CHE T. Chen, G. T. Hefter, R. Buchner. J. Solution Chem.34, 1059 (2005).Search in Google Scholar

2005PBa 10.1351/pac200577040739, K. J. Powell, P. L. Brown, R. H. Byrne, T. Gajda, G. Hefter, S. Sjöberg, H. S. Wanner. Pure Appl. Chem.77, 739 (2005).Search in Google Scholar

2006ARa C. Akilan, N. Rohman, G. T. Hefter, R. Buchner. Chem. Phys. Chem.7, 2319 (2006).Search in Google Scholar

2007LUO 10.1016/j.gca.2006.09.019, Y. Luo, F. J. Millero. Geochim. Cosmochim. Acta71, 326 (2007).Search in Google Scholar PubMed PubMed Central

2007PBa 10.1351/pac200779050895, K. J. Powell, P. L. Brown, R. H. Byrne, T. Gajda, G. Hefter, S. Sjöberg, H. Wanner. Pure Appl. Chem.79, 895 (2007).Search in Google Scholar

2007XIE 10.1021/es071517e, L. Xie, D. E. Giammar. Environ. Sci. Technol.41, 8050 (2007).Search in Google Scholar PubMed

2008SOL 10.1016/j.marchem.2008.01.004, A. L. Soli, Z. I. Stewart, R. H. Byrne. Mar. Chem.110, 1 (2008).Search in Google Scholar

2008GAM 10.1351/pac200880020233, H. Gamsjäger, J. W. Lorimer, P. Scharlin, D. G. Shaw. Pure Appl. Chem.80, 233 (2008).Search in Google Scholar

2009PET L. D. Pettit, K. J. Powell. SC-Database, IUPAC Stability Constants Database. Release 5.8. IUPAC; Academic Software, Otley, UK (2009); for availability, see <www.iupac.org/publications/scdb> or <www.acadsoft.co.uk>.Search in Google Scholar

Published Online: 2009-10-29
Published in Print: 2009-10-31

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